Beilstein J. Org. Chem.2024,20, 921–930, doi:10.3762/bjoc.20.82
.
Keywords: acyl fluorides; amides; benzothiazoliumsalts; carboxylic acids; deoxygenative reactions; Introduction
Acyl fluorides are attracting much attention as versatile reagents for different applications in organic synthesis. In addition to their use as sources of fluoride ions, they are most commonly
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Graphical Abstract
Figure 1:
Advantages of acyl fluorides compared to acyl chlorides, previous work on BT-SRF reagents [29-33] and a su...
Beilstein J. Org. Chem.2021,17, 83–88, doi:10.3762/bjoc.17.8
directly from readily available alcohols.
Keywords: alcohols; benzothiazoliumsalts; deoxygenative reactions; fluorine; perfluoroalkylthiolation; thioethers; Introduction
The incorporation of fluorine-containing groups into organic molecules to modulate their biological or physical properties is nowadays
reactions of readily available aliphatic alcohols. Some features of this process led us to consider whether related benzothiazoliumsalts featuring longer-chain SRF substituents could serve as practical reagents for investigating nucleophilic perfluoroalkylthiolation reactions. Firstly, the simple two-step
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Graphical Abstract
Scheme 1:
Synthetic routes towards perfluoroalkyl thioethers.